Here』s a quick CSS snippet used to center an entire form. Replace 2 in #gform_wrapper_2 with the id of your form.
/* keep it mobile friendly by only applying these styles for larger viewports */
@media only screen and (min-width: 641px) {
body #gform_wrapper_2 {
max-width: 50%;
margin: 0 auto;
}
body #gform_wrapper_2 .gfield .ginput_container,
body #gform_wrapper_2 .gfield .gfield_description,
body #gform_wrapper_2 div.ginput_complex label,
body #gform_wrapper_2 input:not([type='radio']):not([type='checkbox']):not([type='submit']),
body #gform_wrapper_2 select,
body #gform_wrapper_2 textarea {
text-align:center;
}
body #gform_wrapper_2 .top_label .gfield .gfield_label {
text-align: center;
display: block;
}
body #gform_wrapper_2 .gform_footer,
body #gform_wrapper_2 .gform_page_footer{
text-align: center;
}
}
Reference: Where to Put Your Custom CSS
If using any caching solution, be sure you have flushed the cache and turned it off while making CSS changes.